Polyoxometalate-based 3D porous framework with inorganic molecular nanocage units
نویسندگان
چکیده
منابع مشابه
Water decontamination by polyoxometalate-functionalized 3D-printed hierarchical porous devices.
The design of organic-inorganic hybrid composites has revolutionized application-driven materials design. Here, we show how hierarchically structured, 3D-printed ABS polymers can be surface-functionalized with lacunary polyoxometalate anions ([α-PW9O34]9-) featuring heavy-metal binding sites. The resulting composite is highly porous and can be used for the removal of transition-metal pollutants...
متن کاملStructural and catalytic performance of a polyoxometalate-based metal-organic framework having a lanthanide nanocage as a secondary building block.
A polyoxometalate-based lanthanide-organic framework was achieved using the {[Ho(4)(dpdo)(8)(H(2)O)(16)BW(12)O(40)] (H(2)O)(2)}(7+) nanocage as a secondary building block for the heterogeneous catalysis of phosphodiester cleavage in an aqueous solution.
متن کامل3D pure inorganic framework based on polymolybdovanadate possessing photoelectric properties.
The first 3D pure inorganic framework based on heteropolymolybdate anion [V2Mo16O58](10-) has been synthesized and its photoelectric properties demonstrated.
متن کاملHeterogeneous Catalysis of Polyoxometalate Based Organic–Inorganic Hybrids
Organic-inorganic hybrid polyoxometalate (POM) compounds are a subset of materials with unique structures and physical/chemical properties. The combination of metal-organic coordination complexes with classical POMs not only provides a powerful way to gain multifarious new compounds but also affords a new method to modify and functionalize POMs. In parallel with the many reports on the synthesi...
متن کاملAn all-inorganic polyoxometalate-polyoxocation chemical garden.
Herein, we show it is possible to produce wholly inorganic chemical gardens from a cationic polyoxometalate (POM) seed in an anionic POM solution, demonstrating a wholly POM-based chemical garden system that produces architectures over a wide concentration range. Six concentration dependent growth regimes have been discovered and characterized: clouds, membranes, slugs, tubes, jetting and budding.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Chemical Sciences
سال: 2017
ISSN: 0974-3626,0973-7103
DOI: 10.1007/s12039-017-1265-7